Impedance spectroscopy of Si whiskers in the range of metal-insulator transition
DOI:
https://doi.org/10.20535/RADAP.2013.55.97-106Keywords:
silicon, whiskers, metal–insulator transitions, impedance spectroscopyAbstract
Introduction. The paper deals with investigation of impedance spectroscopy of Si whiskers with doping concentration in the vicinity to metal-insulator transition in the region of low (4,2 – 70 K) temperature and frequency range 0,01 – 250x103 Hz. Experimental results. The silicon whiskers were grown by chemical vapour deposition method in closed bromine system. The whiskers of 40x10-6 m in diameter have boron concentration from 2×1018 to 2×1019 сm-3. The impedance spectroscopy of Si whiskers was investigated with use of Lock-in amplifier in the region of low (4,2 – 70 K) temperature and frequency range 0,01 – 250 x 103 Hz. The investigations showed that in the range of zone conductance (T= 30 – 70 K) the whisker impedance has inductive character, while at the range of impurity conductance (T = 4,2 – 20 K) impedance changes to capacity character. The reduction of impurity concentration at dielectric side of metal-insulator transition leads to decrease of the whisker capacity in the range of low temperatures. Discussion. An inductive character of whisker impedance is explained skin-effect of conductance in thin whisker, while capacity character of the whisker impedance is connected with hopping conductance on impurity band. Conclusions. Character of changes of Si whisker impedance conductance is discussed in the frame of hopping conductance on impurity band, which takes place at low temperatures.References
Література
Дружинін А.О Ниткоподібні кристали кремнію, германію та їх твердих розчинів у сенсорній електроніці / Островський І.П., Когут Ю.Р. : Монографія.– Львів, НУ «Львівська політехніка», 2010. – 200 с. [Publ.]
Mora-Sero I. Implications of the Negative Capacitance Observed at Forward Bias in Nanocomposite and Polycrystalline Solar Cells / I. Mora-Sero, J. Bisquert // Nano Letters. – 2006. – Vol. 6. – № 4. – p. 640−650. doi: 10.1021/nl052295q
Bisquert J. Inductive behaviour by charge-transfer and relaxation in solid-state electrochemistry / J. Bisquert, H. Randriamahazaka, G. Garsia-Belmonte // Electrochimica Acta. – 2005. – Vol. 51, № 4 – p. 627−640. doi: 10.1016/j.electacta.2005.05.025
Mora-Sero I. Implications of the Negative Capacitance Observed at Forward Bias inanocomposite and Polycrystalline Solar Cells / I. Mora-Sero, J. Bisquert, F. Fabregat-Santiago, G. Garcia Belmonte // Nano Letters. – 2006. – Vol. 6, № 4. – p. 640-650. doi: 10.1021/nl052295q
Аверкиев Н.С. Частотная зависимость емкости в структурах на основе пористого кремния / Н.С. Аверкиев, Л.М. Капитонова, А.А. Лебедев, А.Д. Ременюк // Физика и техника полупроводников. – 1996. – Т. 30, № 12. – c. 2178-2182. [Publ.]
Werner J. Origin of the Excess Capacitance at Intimate Schottky Contacts / A. Levi, R.T. Tung // Physical review letters. – 1988. – Vol. 60. – p.53-56. doi: 10.1103/PhysRevLett.60.53
Wu X. Negative capacitance at metal-semiconductor interfaces / X. Wu, E.S. Yang, H.L. Evans // Journal of Applied Physics. – 1990. – Vol. 68. – p. 2845-2848. doi: 10.1063/1.346442
Steiner K. Inductive reactances and excess capacitances at WNx/n–GaAs Schottky gate contacts / K. Steiner, N. Uchitami, N. Toyoda // Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures. – 1990. – Vol. 8, № 5. – p. 1113–1116. doi: 10.1116/1.584926
Поклонский Н.А. Отрицательная емкость (импенданс индуктивного типа) кремниевых р+– n- переходов, облученных быстрыми електронами / Н.А. Поклонский, С.В. Шпаковский, Н.И. Горбачу, С.Б. Ластовский // Физика и техника полупроводников. – 2006. – Т. 40, № 7. – с. 824-828. doi: 10.1134/S1063782606070128
Дружинін А.О. Електропровідність та магнетоопір ниткоподібних кристалів кремнію // А.О. Дружинін, І.П. Островський, Ю.М. Ховерко, Р.М. Корецький, С.Ю. Яцухненко // Вісник Національного університету “Львівська політехніка”, Електроніка. – 2012. – № 734. – С. 91-97. [Publ.]
Ермаков А.П. Механические свойства нитевидных кристаллов кремния и германия при внешних воздействиях и методы их изучения : дис. на соискание наук. ступеня канд. техн. наук : спец. 01.04.07 «Физика твердого тела» / А. П. Ермаков ; Воронежский государственный технический университет. – Воронеж, 2000.
References
Druzhynin A.O., Ostrovskyi I.P., Kogut Yu.R. (2010) Nytkopodibni krystaly kremniiu, germaniiu ta yikh tverdykh rozchyniv u sensornii elektronitsi [Whiskers of silicon, germanium and their solid solutions in sensors electronic]. Lviv, Lvivska politekhnika Publ., 200 p. [Publ.]
Mora-Sero I., Bisquert J. (2006) Implications of the Negative Capacitance Observed at Forward Bias in Nanocomposite and Polycrystalline Solar Cells. Nano Letters, Vol. 6., No 4, pp. 640−650. doi: 10.1021/nl052295q
Bisquert J., Randriamahazaka H., Garsia-Belmonte G. (2005) Inductive behaviour by charge-transfer and relaxation in solid-state electrochemistry. Electrochimica Acta, Vol. 51, No 4, pp. 627−640. doi: 10.1016/j.electacta.2005.05.025
Mora-Sero I., Bisquert J., Fabregat-Santiago F., Garcia Belmonte G. (2006) Implications of the Negative Capacitance Observed at Forward Bias inanocomposite and Polycrystalline Solar Cells. Nano Letters, Vol. 6, No. 4. pp. 640-650. doi: 10.1021/nl052295q
Averkiev N.S., Kapitonova L.M., Lebedev A.A., Remeniak A.D. (1996) Chastotnaia zavisimost yemkosti v strukturakh na osnove porystogo kremniia []. Physics and Technics of Semiconductors. Vol. 30, No 12, pp. 2178-2182.
Werner J., Levi A.F.J., Tung R.T., Anzlowar M., Pinto M. (1988). Origin of the excess capacitance at intimate Schottky contacts. Physical review letters. Vol. 60, pp. 53-56. doi: 10.1103/PhysRevLett.60.53
Wu X., Yang E.S., Evans H.L. (1990) Negative capacitance at metal-semiconductor interfaces. Journal of Applied Physics, Vol. 68, pp. 2845-2848. doi: 10.1063/1.346442
Steiner K., Uchitami N., Toyoda N. (1990) Inductive reactances and excess capacitances at WNx/n–GaAs Schottky gate contacts. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 8, No. 5, pp. 1113–1116. doi: 10.1116/1.584926
Poklonski N. A., Shpakovski S. V., Gorbachuk N. I., Lastovskii S. B. (2006) Negative capacitance (impedance of the inductive type) of silicon p+–n junctions irradiated with fast electrons. Semiconductors. Vol. 40, No 7, pp. 803-807. doi: 10.1134/S1063782606070128
Druzhinin A.A., Ostrovskii I.P., Khoverko Yu.M., Koretskyy R.M., Yatsukhnenko S.Yu. (2012) Elektroprovidnist ta magnetoopir nytkopodibnyh krystaliv kremniiu. Visnyk of Lviv Polytechnic National University, Electronics, no. 734, pp. 91-97. [Publ.]
.Ermakov A.P. Mehanicheskie svoystva nitevidnyih krystallov kremniia i germaniia pry vneshnyh vozdeystviyah i metodyi yh izucheniya. Dis. kand. tehn. nauk. [Mechanical properties of whiskers of silicon and germanium caused by external influences and methods of their study. Cand. tech. sci. diss.]. Voronezh, 2000.
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